As the reform of the education system in colleges and universities progresses, physical education teaching has gained increasing attention and recognition from various sectors. Among the various sports, volleyball stands out as a key component of the college physical education curriculum. It is highly favored by students, who often choose it as their top option for physical education courses. Volleyball can not only enhance physical quality but also develop the psychological resilience. Therefore, teachers must explore effective training methods for volleyball instruction to improve students’ physical fitness, foster teamwork, strengthen their mental resilience, and ultimately support their overall development. Therefore, this paper combined with the above background to carry out research, analyzes the practical significance of college volleyball teaching, the existing problems in the current teaching, and puts forward effective training methods.