Against the background that vocational undergraduate education focuses on cultivating high-level technical and skilled talents, this paper, from the student perspective and taking “Five-Education Integration” (moral, intellectual, physical, aesthetic and labor education) as the theoretical framework, explains the three-dimensional connotation of moral, intellectual, physical, aesthetic and labor education. It analyzes the internal logic of the deep coupling between the goals of the “Five Educations” (talent cultivation objectives) and the paths of the “Five-Comprehensive” (all-staff, all-process, all-dimension, all-factor, all-time and space, implementation paths). In view of the dilemmas faced by students in practicing the “Five Educations”, such as cognitive bias, disconnection between moral and labor education and practice, and lack of subjective consciousness, this paper puts forward a three-dimensional practice path: taking professional learning as the core to radiate the integration of the five educations, taking the campus second classroom as the platform to expand literacy, and taking career planning as the guide to strengthen self-management. It provides practical references for vocational undergraduate students to achieve both moral and technical development and all-round development, and helps them grow into high-quality talents adapting to career needs.